1,1,3,3-Tetraphenyl-1,2,3-triphosphenium tetrachloroaluminate dichloromethane solvate
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چکیده
منابع مشابه
[μ-Bis(diphenylphosphanyl-κP)methane]decacarbonyltri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
In the title compound, [Re(3)(μ-H)(3)(C(25)H(22)P(2))(CO)(10)]·CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis-(diphenyl-phosphan-yl)methane ligand bridges two Re atoms. Neglecting the Re-Re inter-actions, each Re atom is in a slightly distorted octa-hedral coordination environment. The dichloro-methane solvent mol-ec...
متن کاملCrystal structure of trans-(dicyano)bis(triphenylphosphine)palladium(II) dichloromethane solvate.
was obtained from the reaction of Pd(PPh3)4 with Me3SiCN (1:1 molar ratio) in benzene (at 80 ̊C for 2 h). Crystals suitable for X-ray diffraction analysis were obtained by recrystallization from a mixture of CH2Cl2 and C6H6 (ca. 1:4 by volume). Table 1 summarizes the crystal and experimental data. During the data collection at room temperature, decay was not observed. All intensity data were cor...
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In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN(7))]·CH(2)Cl(2) (9-MeAde = 9-methyl-adenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyl-adenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric...
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The title compound, C(46)H(40)N(4)O(2)·0.33C(6)H(12), was obtained unintentionally as a product of an attempted synthesis of a cadmium(II) complex of the [2,6-{PhSe(CH(2))(2)N=CPh}(2)C(6)H(2)(4-Me)(OH)] ligand. The full tetra-imino-diphenol macrocyclic ligand is generated by the application of an inversion centre. The macrocyclic ligand features strong intra-molecular O-H⋯N hydrogen bonds. The ...
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A member of the NADPH oxidase subunits, p40 plays an important role in the regulation of NADPH oxidase activity and the subsequent production of reactive oxygen species (ROS). In this study, we show that mouse p40 is a novel transcriptional target of the aryl hydrocarbon receptor (AhR), known as a dioxin receptor or xenobiotic receptor, in the liver. Treatment of mice with 3-methylcholanthrene ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2005
ISSN: 1600-5368
DOI: 10.1107/s1600536805000656